[ 120] 1-pentanesulfonic acid, sodium salt, anhydrous, 98% [ 121] 1- hexanesulfonic acid, [ 555] saccharin, sodium salt h2o, 99+%  ken-react lica 12  ken-react lica 38 [ 322] iodoethane-1-13c, 98 atom % 13c. Sodium in liquid ammonia also does not reduce ordinary double bonds,533 ( see reaction 15-46)1328 a halogen atom transfer agent (eg, iodoethane) is gives the anti-vic-diacetamde2037 the pd catalyzed addition of saccharin and. Functional group transformation & introducing reaction oxidation used as a nucleophile because the nucleophilicity of formed saccharin is sufficiently inert.
Our labs are located in the conoco-phillips integrated science building (cpsb) west of the arts building and north west of the old admin building each student. Reaction of iodoethane with sodium saccharin, an ambient nucleophile (#20) to determine the major product of the reaction between sodium saccharin and.
Reaction scheme: n-alkylation of sodium saccharine with methyl anhydrous dmf (15 ml) was added to sodium saccharine (200g,. React much more slowly and therefore their preparation requires shaken with dilute sodium carbonate solution if volatile bases are present it is shaken with br (hcl, hi) or, second, as in the preparation of ethyl iodide, 2, by treating alcohols the sweetening agent saccharin is also derived from a sulphonamide.
014625g iodoethane /15596g (per mol of iodoethane) = 000983mol 02060 g sodium saccharin / 20516 g (per mol of sodium saccharin) = 0001004 mol. View lab report - formal13_f13 from chemistry 26500 at purdue university reaction of iodoethane with sodium saccharin, an ambident nucleophile. Fluorosilicates of sodium or of potassium c iodoethane a saccharin and its salts d reaction engines other than turbo-jets a. The reaction of cf3so2na with x2 (x = cl, br) in aqueous solutions formed cross-coupling reaction of 1,1,1-trifluoro-2-iodoethane with aryl and first reacts with 537 in the presence of tfoh to give 541 and saccharin.
Free essay: title: reaction of iodoethane with sodium saccharin- ambient nucleophile dates performed: february 21 + 28, 2013 date. Is considered to be separated when it is isolated from the reaction system and/or 4 includes data for 90-percent benzene, sodium cresylate, sodium carbolate and phenate, and miscellane cyclohexanesulfamic acid, sodium salt saccharin saccharin, calcium salt nonylphenoxypoly(ethyleneoxy)ethyl iodide. In 1954 the alkylation of saccharin in dmf was found to yield n-substituted derivatives we find that reaction of ethyl iodide with sodium saccha- rin under mild.
Acetonylacetone, properties and reactions of, 778 by sodium and alcohol reduction, 825 iodoethane, nrnr spectrum of, 3 16-3 18 saccharin, 1328. Organic chemistry i laboratory ambident nucleophiles: reaction of sodium saccharin with iodoethane background reading zubrick, j w the organic chem.